Rainfall estimation using moving cars as rain gauges – laboratory experiments Hydrology and Earth System Sciences DOI 10.5194/hess-17-4701-2013 28 November 2013 The spatial assessment of short time-step precipitation is a challenging task. Low density of observation networks, as well as the bias in radar rainfall estimation motivated the new idea of exploiting cars as moving rain gauges with windshield wipers or optical sensors as measurement devices. Read more
Arctic stratospheric dehydration – Part 1: Unprecedented observation of vertical redistribution of water Atmospheric Chemistry and Physics DOI 10.5194/acp-13-11503-2013 27 November 2013 This paper presents high-resolution measurements of water vapour, aerosols and clouds in the Arctic stratosphere in January and February 2010 carried out by in situ instrumentation on balloon sondes and high-altitude aircraft combined with satellite observations. Read more
Quantifying aerosol mixing state with entropy and diversity measures Atmospheric Chemistry and Physics DOI 10.5194/acp-13-11423-2013 25 November 2013 This paper presents the first quantitative metric for aerosol population mixing state, defined as the distribution of per-particle chemical species composition. Read more
Paleosols in the Transantarctic Mountains: indicators of environmental change Solid Earth DOI 10.5194/se-4-451-2013 20 November 2013 Paleosols on unconsolidated deposits are emphasized in this study. Examples are given from the McMurdo Dry Valleys (78° S) and two outlet glaciers in the central and southern TAMS, including the Hatherton–Darwin Glacier region (80° S) and the Beardmore Glacier region (85°30’ S). Read more
Inverse streamflow routing Hydrology and Earth System Sciences DOI 10.5194/hess-17-4577-2013 19 November 2013 Here we develop a methodology to invert the routing process, i.e., to derive the spatially distributed runoff from streamflow (e.g., measured at gauge stations) by inverting an arbitrary linear routing model using fixed interval smoothing. Read more
Peak glacial 14C ventilation ages suggest major draw-down of carbon into the abyssal ocean Climate of the Past DOI 10.5194/cp-9-2595-2013 15 November 2013 Here we present a new, though still fragmentary, ocean-wide Δ14C data set showing that during the Last Glacial Maximum (LGM) and Heinrich Stadial 1 (HS-1) the maximum 14C age difference between ocean deep waters and the atmosphere exceeded the modern values by up to 1500 14C yr, in the extreme reaching 5100 14C yr. Read more
Heterogeneous formation of polar stratospheric clouds – Part 2: Nucleation of ice on synoptic scales Atmospheric Chemistry and Physics DOI 10.5194/acp-13-10769-2013 6 November 2013 This paper provides compelling evidence for the importance of heterogeneous nucleation, likely on solid particles of meteoritic origin, and of small-scale temperature fluctuations, for the formation of ice particles in the Arctic stratosphere. Read more
Where to find 1.5 million yr old ice for the IPICS “Oldest-Ice” ice core Climate of the Past DOI 10.5194/cp-9-2489-2013 5 November 2013 The recovery of a 1.5 million yr long ice core from Antarctica represents a keystone of our understanding of Quaternary climate, the progression of glaciation over this time period and the role of greenhouse gas cycles in this progression. Here we tackle the question of where such ice may still be found in the Antarctic ice sheet Read more
Ratios among atmospheric trace gases together with winds imply exploitable information for bird navigation: a model elucidating experimental results Biogeosciences DOI 10.5194/bg-10-6929-2013 4 November 2013 A model of avian goal-oriented navigation is described that is based on two empirical findings building a bridge from ornithology to atmospheric chemistry. Read more
A thermodynamic approach to link self-organization, preferential flow and rainfall–runoff behaviour Hydrology and Earth System Sciences DOI 10.5194/hess-17-4297-2013 1 November 2013 This study investigates whether a thermodynamically optimal hillslope structure can, if existent, serve as a first guess for uncalibrated predictions of rainfall–runoff. Read more
Filamentary structure in chemical tracer distributions near the subtropical jet following a wave breaking event Atmospheric Chemistry and Physics DOI 10.5194/acp-13-10517-2013 31 October 2013 This paper presents a set of observations and analyses of trace gas cross sections in the extratropical upper troposphere/lower stratosphere (UTLS). Read more
Nitrous Oxide (N2O) production in axenic Chlorella vulgaris microalgae cultures: evidence, putative pathways, and potential environmental impacts Biogeosciences DOI 10.5194/bg-10-6737-2013 25 October 2013 Using antibiotic assays and genomic analysis, this study demonstrates nitrous oxide (N2O) is generated from axenic Chlorella vulgaris cultures. In batch assays, this production is magnified under conditions favouring intracellular nitrite accumulation, but repressed when nitrate reductase (NR) activity is inhibited. Read more
Global monitoring of terrestrial chlorophyll fluorescence from moderate-spectral-resolution near-infrared satellite measurements: methodology, simulations, and application to GOME-2 Atmospheric Measurement Techniques DOI 10.5194/amt-6-2803-2013 25 October 2013 Here, we describe a new methodology to retrieve global far-red fluorescence information; we use hyperspectral data with a simplified radiative transfer model to disentangle the spectral signatures of three basic components: atmospheric absorption, surface reflectance, and fluorescence radiance. An empirically based principal component analysis approach is employed, primarily using cloudy data over ocean, to model and solve for the atmospheric absorption. Read more
Cloud-resolving simulations of mercury scavenging and deposition in thunderstorms Atmospheric Chemistry and Physics DOI 10.5194/acp-13-10143-2013 15 October 2013 This study examines dynamical and microphysical features of convective clouds that affect mercury (Hg) wet scavenging and concentrations in rainfall. Read more
Carbonate mineral saturation states in the East China Sea: present conditions and future scenarios Biogeosciences DOI 10.5194/bg-10-6453-2013 11 October 2013 To assess the impact of rising atmospheric CO2 and eutrophication on the carbonate chemistry of the East China Sea shelf waters, saturation states (Ω) for two important biologically relevant carbonate minerals were calculated throughout the water column. Read more
A novel salinity proxy based on Na incorporation into foraminiferal calcite Biogeosciences DOI 10.5194/bg-10-6375-2013 9 October 2013 This study investigates the impact of salinity on foraminiferal Na/Ca values by laser ablation ICP-MS analyses of specimens of the benthic foraminifer Ammonia tepida cultured at a range of salinities (30.0–38.6). Read more
Critical impacts of global warming on land ecosystems Earth System Dynamics DOI 10.5194/esd-4-347-2013 8 October 2013 Here we present a macro-scale analysis of climate change impacts on terrestrial ecosystems based on newly developed sets of climate scenarios featuring a step-wise sampling of global mean temperature increase between 1.5 and 5 K by 2100. Read more
Remote sensing of LAI, chlorophyll and leaf nitrogen pools of crop- and grasslands in five European landscapes Biogeosciences DOI 10.5194/bg-10-6279-2013 7 October 2013 The purpose of this study is to use field-based and satellite remote-sensing-based methods to assess leaf nitrogen pools in five diverse European agricultural landscapes located in Denmark, Scotland (United Kingdom), Poland, the Netherlands and Italy. Read more
Naphthalene SOA: redox activity and naphthoquinone gas–particle partitioning Atmospheric Chemistry and Physics DOI 10.5194/acp-13-9731-2013 2 October 2013 Chamber secondary organic aerosol from low-NOx photooxidation of naphthalene by hydroxyl radical was examined with respect to its redox cycling behaviour using the dithiothreitol assay. Read more
Multiple stressors of ocean ecosystems in the 21st century: projections with CMIP5 models Biogeosciences DOI 10.5194/bg-10-6225-2013 2 October 2013 Ocean ecosystems are increasingly stressed by human-induced changes of their physical, chemical and biological environment. Here, we use the most recent simulations performed in the framework of the Coupled Model Intercomparison Project 5 to assess how stressors such as warming, acidification deoxygenation and changes in primary productivity by marine phytoplankton, may evolve over the course of the 21st century. Read more