A joint thermal and electromagnetic diagnostics approach for the inspection of thick walls Geoscientific Instrumentation, Methods and Data Systems DOI 10.5194/gi-6-81-2017 8 February 2017 A numerical inversion approach to detect and localize inclusions in thick walls under quasi-periodic natural solicitations is presented. It is based on a preliminary analysis of surface temperature field evolution with time. This analysis is improved by taking advantage of a priori information provided by ground-penetrating radar reconstructions. In this way, it is possible to improve the accuracy of the images achievable with the stand-alone thermal reconstruction method. Read more
A high-altitude balloon experiment to probe stratospheric electric fields from low latitudes Annales Geophysicae DOI 10.5194/angeo-35-189-2017 3 February 2017 Results from a high-altitude balloon experiment conducted from a low-latitude station in India are presented in this work. The objectives of this experiment were to probe and understand the processes driving the various electric field sources at low latitudes. During this experiment, electric fields in the range of 5–6 mV m−1 were observed at the balloon float altitude of 35 km. Atmospheric waves of few 100 km horizontal wavelength are suggested to be a potential source of these electric fields. Read more
Halogen chemistry reduces tropospheric O3 radiative forcing Atmospheric Chemistry and Physics DOI 10.5194/acp-17-1557-2017 31 January 2017 We model pre-industrial to present day changes using the GEOS-Chem global chemical transport model with halogens (Cl, Br, I). The model better captures pre-industrial O3observations with halogens included. Halogens buffer the tropospheric forcing of O3(RFTO[~3~]) from pre-industrial to present day, reducing RFTO[~3~]by 0.087 Wm−2. This reduction is greater than that from halogens on stratospheric O3(−0.05 Wm−2). This suggests that models that do not include halogens will overestimate RFTO[~3~]by ~ 25%. Read more
Decadal changes in global surface NOx emissions from multi-constituent satellite data assimilation Atmospheric Chemistry and Physics DOI 10.5194/acp-17-807-2017 27 January 2017 Global surface emissions of nitrogen oxides (NOx) over a 10-year period (2005–2014) are estimated from assimilation of multiple satellite datasets. We present detailed distributions of the estimated NOxemission distributions for all major regions, the diurnal, seasonal, and decadal variability. The estimated emissions show a positive trend over India, China, and the Middle East, and a negative trend over the United States, southern Africa, and western Europe. Read more
Snow fracture in relation to slab avalanche release: critical state for the onset of crack propagation The Cryosphere DOI 10.5194/tc-11-217-2017 27 January 2017 Based on DEM simulations we developed a new model for the onset of crack propagation in snow slab avalanche release. The model reconciles past approaches by considering the complex interplay between slab elasticity and the mechanical behavior of the weak layer including its structural collapse. The model agrees with extensive field data and can reproduce crack propagation on low-angle terrain and the decrease in critical crack length with increasing slope angle observed in numerical experiments. Read more
Representing nighttime and minimum conductance in CLM4.5: global hydrology and carbon sensitivity analysis using observational constraints Geoscientific Model Development DOI 10.5194/gmd-10-321-2017 23 January 2017 Earth’s terrestrial surface influences climate by exchanging carbon and water with the atmosphere through stomatal pores. However, most land-surface models, used to predict global carbon and water fluxes, estimate that water lost through stomata is less than what observations show. In this study, we integrate plant water loss data from 204 species into a global land surface model, finding that global estimates of plant water loss increase, soil moisture decreases, and carbon gain also decreases. Read more
Determination of the atmospheric lifetime and global warming potential of sulfur hexafluoride using a three-dimensional model Atmospheric Chemistry and Physics DOI 10.5194/acp-17-883-2017 20 January 2017 Sulfur hexafluoride (SF6) is a very potent greenhouse gas, which is present in the atmosphere only through its industrial use, for example as an electrical insulator. To estimate accurately the impact of SF6emissions on climate we need to know how long it persists in the atmosphere before being removed. Previous estimates of the SF6lifetime indicate a large degree of uncertainty. Here we use a detailed atmospheric model to calculate a current best estimate of the SF6lifetime. Read more
Chemical oxidative potential of secondary organic aerosol (SOA) generated from the photooxidation of biogenic and anthropogenic volatile organic compounds Atmospheric Chemistry and Physics DOI 10.5194/acp-17-839-2017 19 January 2017 Secondary organic aerosols (SOA) comprise a significant fraction of particulate matter (PM) and may have health implications. The water-soluble oxidative potentials of various SOA systems were determined using dithiothreitol consumption. Results from this study demonstrate that precursor identity was more influential than reaction condition in determining SOA oxidative potential and highlight a need to consider SOA contributions from anthropogenic hydrocarbons to PM-induced health effects. Read more
Radical chemistry at a rural site (Wangdu) in the North China Plain: observation and model calculations of OH, HO2 and RO2 radicals Atmospheric Chemistry and Physics DOI 10.5194/acp-17-663-2017 13 January 2017 In this study, we performed accurate OH measurements as well as selective HO2 and RO2 measurements at a rural site in North China Plain with state-of-the-art instruments newly developed. We confirmed the previous discovery on the enhancement of the OH in low NOx with which little O3 production was associated, and we found a missing RO2 source in high NOx which promoted higher O3 production. Our results are of vital importance for ozone abatement strategies currently under discussion for China. Read more
A comprehensive one-dimensional numerical model for solute transport in rivers Hydrology and Earth System Sciences DOI 10.5194/hess-21-99-2017 5 January 2017 In this study a comprehensive model was developed that combines numerical schemes with high-order accuracy for solution of the advection–dispersion equation considering transient storage zones term in rivers. In developing the subjected model (TOASTS), for achieving better accuracy and applicability, irregular-cross sections and unsteady flow regime were considered. For this purpose the QUICK scheme due to its high stability and low approximation error has been used for spatial discretization. Read more
A missing source of aerosols in Antarctica – beyond long-range transport, phytoplankton, and photochemistry Atmospheric Chemistry and Physics DOI 10.5194/acp-17-1-2017 2 January 2017 This paper summarizes two field measurements of particles and gases made in coastal Antarctica and represents the first real-time composition measurements of particles in this understudied area of the world. Using the combined data from both field measurements, we find that there is a constant background of particles in coastal Antarctica and that they are mostly sulfate. Seasonal transitions from winter to spring add additional particles, and that from spring to summer adds additional sulfate. Read more
Model sensitivity studies of the decrease in atmospheric carbon tetrachloride Atmospheric Chemistry and Physics DOI 10.5194/acp-16-15741-2016 20 December 2016 Carbon tetrachloride (CCl4) is a compound which, when released into the atmosphere, can cause depletion of the stratospheric ozone layer. Its emissions are controlled under the Montreal Protocol, and its atmospheric abundance is slowly decreasing. However, this decrease is not as fast as expected based on estimates of its emissions and its atmospheric lifetime. We have used an atmospheric model to look at the uncertainties in the CCl4lifetime and to examine the impact on its atmospheric decay. Read more
Slow strain waves in blocky geological media from GPS and seismological observations on the Amurian plate Nonlinear Processes in Geophysics DOI 10.5194/npg-23-467-2016 19 December 2016 We have obtained new evidence of the existence of strain waves in the Earth based on a statistical analysis of the dynamics of seismicity along the northern boundary of the Amurian plate and the data derived from in situ GPS experimental observations. Our results (the periodicity of the seismic components, spatial cycles of the seismicity maxima and migration rate of earthquakes) allow us to identify the dynamics of seismicity along the northern boundary of the Amurian plate as a wave process. Read more
Non-destructive evaluation of moisture content in wood using ground-penetrating radar Geoscientific Instrumentation, Methods and Data Systems DOI 10.5194/gi-5-575-2016 16 December 2016 Ground-penetrating radar (GPR) is a powerful tool that uses electromagnetic waves to obtain 3-dimensional images of natural or man-made structures and subsoil. It is employed in a large variety of applications in which non-destructive investigations are required. This paper deals with the use of GPR for the evaluation of moisture content in wood. The results of our work are of great interest for the preservation of timber structures, as moisture content is highly relevant to wood deterioration. Read more
Last Interglacial climate and sea-level evolution from a coupled ice sheet–climate model Climate of the Past DOI 10.5194/cp-12-2195-2016 15 December 2016 We simulate the climate, ice sheet, and sea-level evolution during the Last Interglacial (~ 130 to 115 kyr BP), the most recent warm period in Earth’s history. Our Earth system model includes components representing the atmosphere, the ocean and sea ice, the terrestrial biosphere, and the Greenland and Antarctic ice sheets. Our simulation is in good agreement with available data reconstructions and gives important insights into the dominant mechanisms that caused ice sheet changes in the past. Read more
Graffiti for science – erosion painting reveals spatially variable erosivity of sediment-laden flows Earth Surface Dynamics DOI 10.5194/esurf-4-885-2016 15 December 2016 Spatial bedrock erosion data from stream channels are important for engineering issues and landscape evolution model assessment. However, acquiring such data is challenging and only few data sets exist. Detecting changes in repeated photographs of painted bedrock surfaces easily allows for semi-quantitative conclusions on the spatial distribution of sediment transport and its effects: abrasion on surfaces facing the streamflow and shielding of surfaces by abundant sediment. Read more
North American regional climate reconstruction from ground surface temperature histories Climate of the Past DOI 10.5194/cp-12-2181-2016 14 December 2016 Within the framework of the PAGES NAm2k project, we estimated regional trends in the ground surface temperature change for the past 500 years in North America. The mean North American ground surface temperature history suggests a warming of 1.8 °C between preindustrial times and 2000. A regional analysis of mean temperature changes over the last 5 centuries shows that all regions experienced warming, but this warming displays large spatial variability and is more marked in high-latitude regions. Read more
The acid-catalyzed hydrolysis of an α-pinene-derived organic nitrate: kinetics, products, reaction mechanisms, and atmospheric impact Atmospheric Chemistry and Physics DOI 10.5194/acp-16-15425-2016 13 December 2016 This study provides new insight into the hydrolysis reaction mechanism, which was elucidated for atmospherically relevant organic nitrates using kinetic measurements, product identification, and theoretical calculations. The results help broaden our knowledge of the organic chemistry that impacts the fate of NOx, ozone production, aerosol phase processing, and aerosol composition. Read more
Use of remote-sensing reflectance to constrain a data assimilating marine biogeochemical model of the Great Barrier Reef Biogeosciences DOI 10.5194/bg-13-6441-2016 7 December 2016 Marine biogeochemical models are often used to understand water quality, nutrient and blue-carbon dynamics at scales that range from estuaries and bays, through to the global ocean. We introduce a new methodology allowing for the assimilation of observed remote sensing reflectances, avoiding the need to use empirically derived chlorophyll-a concentrations. This method opens up the possibility to assimilate of reflectances from a variety of missions and potentially non-satellite platforms. Read more
Significant concentrations of nitryl chloride sustained in the morning: investigations of the causes and impacts on ozone production in a polluted region of northern China Atmospheric Chemistry and Physics DOI 10.5194/acp-16-14959-2016 5 December 2016 This work addresses the unclear global significance of chlorine activation processes in the troposphere. The first high-quality measurement data set of ClNO2in northern China revealed strong ClNO2 production in the residual layers, and demonstrated its significant effects on radical budget and ozone production. Our findings imply the widespread effects of ClNO2 over the polluted regions of northern China, which may increase photochemical and haze pollution. Read more